Uncategorized
To advertise please call 303-447-8531
CU study: Global warming increasing heavy metals in streams
Sep 7th
in Rocky Mountain watershed
tied to warming temperatures
Warmer air temperatures since the 1980s may explain significant increases in zinc and other metal concentrations of ecological concern in a Rocky Mountain watershed, reports a new study led by the U.S. Geological Survey and the University of Colorado Boulder.
Rising concentrations of zinc and other metals in the upper Snake River just west of the Continental Divide near Keystone, Colo., may be the result of falling water tables, melting permafrost and accelerating mineral weathering rates, all driven by warmer air temperatures in the watershed. Researchers observed a fourfold increase in dissolved zinc over the last 30 years during the month of September.
Increases in metals were seen in other months as well, with lesser increases seen during the high-flow snowmelt period. During the study period, local mean annual and mean summer air temperatures increased at a rate of 0.5 to 2.2 degrees Fahrenheit per decade.
Generally, high concentrations of dissolved metals in the Snake River watershed are primarily the result of acid rock drainage, or ARD, formed by natural weathering of pyrite and other metal-rich sulfide minerals in the bedrock. Weathering of pyrite forms sulfuric acid through a series of chemical reactions, and pulls metals like zinc from minerals in the rock and carries these metals into streams.
Increased sulfate and calcium concentrations observed over the study period lend weight to the hypothesis that the increased zinc concentrations are due to acceleration of pyrite weathering. The potential for comparable increases in metals in similar Western watersheds is a concern because of impacts on water resources, fisheries and stream ecosystems. Trout populations in the lower Snake River, for example, appear to be limited by the metal concentrations in the water, said USGS research biologist Andrew Todd, lead researcher on the project.
“Acid rock drainage is a significant water quality problem facing much of the Western United States,” Todd said. “It is now clear that we need to better understand the relationship between climate and ARD as we consider the management of these watersheds moving forward.”
Warmer temperatures and earlier snowmelt runoff have been observed throughout mountainous areas of the western United States where ARD is common, but it is not known if these changes have triggered rising acidity and metal concentrations in other “mineralized” watersheds because of lack of comparable monitoring data, according to the research team.
CU-Boulder Professor Diane McKnight, a collaborator on the project, has generated much of the upper Snake River data through research projects conducted with her students since the mid-1990s. McKnight said students in her environmental engineering and environmental studies class like Caitlin Crouch — a study co-author who received her master’s degree under McKnight — are highly motivated to understand ARD problems.
“Student can see that their research will have direct applications to addressing a critical issue for Colorado,” said McKnight, professor in the civil, environmental and architectural engineering department and a fellow in CU’s Institute of Arctic and Alpine Research.
In cases where ARD is linked directly with past and present mining activities it is called acid mine drainage, or AMD. Another Snake River tributary, Peru Creek, is largely devoid of life due to AMD generated from the abandoned Pennsylvania Mine and smaller mines upstream and has become a target for potential remediation efforts.
The Colorado Division of Reclamation Mining and Safety, in conjunction with other local, state and federal partners, is conducting underground exploration work at the mine to investigate the sources of heavy metals-laden water draining from the mine entrance. The new study by Todd and colleagues has important implications in such mine cleanup efforts because it suggests that establishing attainable cleanup objectives could be difficult if natural background metal concentrations are a “moving target.”
A study on the subject was published in the journal Environmental Science and Technology. Other collaborators include Andrew Manning and Philip Verplanck of USGS. The data analyzed for the study came from INSTAAR, the USGS and the U.S. Environmental Protection Agency.
Wrap your mind around this! photo origami CU Boulder
Aug 27th
wins $2 million NSF grant
The art of origami has inspired children and artists all over the world because of the amazing objects that can be created by folding a simple piece of paper.
Now an engineering research team at the University of Colorado Boulder has won a $2 million grant from the National Science Foundation to develop a light-controlled approach for “self-assembly” mechanisms in advanced devices based on the same principles.
Known as “photo origami,” the idea is supported by NSF’s Emerging Frontiers in Research and Innovation program, which supports interdisciplinary teams working on rapidly advancing frontiers of fundamental engineering research.
CU-Boulder associate professor of mechanical engineering Jerry Qi will lead the team developing the photo origami technique. Collaborators will include CU faculty Robert McLeod of electrical engineering, Kurt Maute of aerospace engineering sciences and Elisabeth “Beth” Stade of mathematics, along with Patrick Mather of Syracuse University.
The ability to transform a flat polymer sheet into a sophisticated, mechanically robust 3-D structure will enable new approaches to manufacturing and design of devices from the microscopic to centimeter scales, according to the team. Examples include using extremely low-weight, high-strength materials to create micro-electromechanical systems with complicated 3-D architectures that can be used for microscopic sensors such as antennas or microphones, and miniature robotic devices for environmental monitoring.
Present barriers to the development of folding and unfolding mechanisms stem from the lack of understanding of scaling laws that allow researchers to generalize results obtained at various size scales, the inability to easily cause matter to “reorient” itself to achieve the desired folding patterns, and challenges in automated, sequential folding.
To overcome these challenges, the CU team will make use of recent fundamental advances in the control of polymer architecture through light-triggered chemical reactions.
“One has to accurately control how much deformation a material should have in order to obtain a precise folding angle and to determine where to fold or stop folding in order to avoid interference in the folding path and form the desired structure,” said McLeod, who will use the interaction of light with material deformation to develop optical waveguide transistors.
In this new form of logic circuit, light triggers the deformation of a soft polymer, which in turn switches the light on or off. In this way, the optical waveguide transistor will enable a structure to be pre-programmed with a folding pattern through a sequential set of switching events controlled by the shape of an origami sheet.
In recent years, CU researchers and their collaborators have made significant progress in using light to control and alter the structure of a polymer. They are able to both bend and stiffen polymer structures and to develop new, soft, shape-memory composite materials through photo-initiation techniques. Shape-memory composites are “smart” materials that have the ability to return from a temporary, deformed shape to their original shape when induced by a trigger.
In addition, the team will work with the local school district to provide research and educational opportunities for K-12 students and teachers.
CU scientists discover a new threat from air pollution
Aug 8th
tied to climate change and human health issues
An international research team led by the University of Colorado Boulder and the University of Helsinki has discovered a surprising new chemical compound in Earth’s atmosphere that reacts with sulfur dioxide to form sulfuric acid, which is known to have significant impacts on climate and health.
The new compound, a type of carbonyl oxide, is formed from the reaction of ozone with alkenes, which are a family of hydrocarbons with both natural and man-made sources, said Roy “Lee” Mauldin III, a research associate in CU-Boulder’s atmospheric and oceanic sciences department and lead study author. The study charts a previously unknown chemical pathway for the formation of sulfuric acid, which can result both in increased acid rain and cloud formation as well as negative respiratory effects on humans.
“We have discovered a new and important, atmospherically relevant oxidant,” said Mauldin. “Sulfuric acid plays an essential role in Earth’s atmosphere, from the ecological impacts of acid precipitation to the formation of new aerosol particles, which have significant climatic and health effects. Our findings demonstrate a newly observed connection between the biosphere and atmospheric chemistry.”
A paper on the subject is being published in the Aug. 9 issue of Nature.
Typically the formation of sulfuric acid in the atmosphere occurs via the reaction between the hydroxyl radical OH — which consists of a hydrogen atom and an oxygen atom with unpaired electrons that make it highly reactive — and sulfur dioxide, Mauldin said. The trigger for the reactions to produce sulfuric acid is sunlight, which acts as a “match” to ignite the chemical process, he said.
But Mauldin and his colleagues had suspicions that there were other processes at work when they began detecting sulfuric acid at night, particularly in forests in Finland — where much of the research took place — when the sun wasn’t present to catalyze the reaction. “There were a number of instances when we detected sulfuric acid and wondered where it was coming from,” he said.
In the laboratory, Mauldin and his colleagues combined ozone — which is ubiquitous in the atmosphere — with sulfur dioxide and various alkenes in a gas-analyzing instrument known as a mass spectrometer hooked up with a “flow tube” used to add gases. “Suddenly we saw huge amounts of sulfuric acid being formed,” he said.
Because the researchers wanted to be sure the hydroxyl radical OH was not reacting with the sulfur dioxide to make sulfuric acid, they added in an OH “scavenger” compound to remove any traces of it. Later, one of the research team members held up freshly broken tree branches to the flow tube, exposing hydrocarbons known as isoprene and alpha-pinene — types of alkenes commonly found in trees and which are responsible for the fresh pine tree scent.
“It was such a simple little test,” said Mauldin. “But the sulfuric acid levels went through the roof. It was something we knew that nobody had ever seen before.”
Mauldin said the new chemical pathway for sulfuric acid formation is of interest to climate change researchers because the vast majority of sulfur dioxide is produced by fossil fuel combustion at power plants. “With emissions of sulfur dioxide, the precursor of sulfuric acid, expected to rise globally in the future, this new pathway will affect the atmospheric sulfur cycle,” he said.
According to the U.S. Environmental Protection Agency, more than 90 percent of sulfur dioxide emissions are from fossil fuel combustion at power plants and other industrial facilities. Other sulfur sources include volcanoes and even ocean phytoplankton. It has long been known that when sulfur dioxide reacts with OH, it produces sulfuric acid that can form acid rain, shown to be harmful to terrestrial and aquatic life on Earth.
Airborne sulfuric acid particles — which form in a wide variety of sizes — play the main role in the formation of clouds, which can have a cooling effect on the atmosphere, he said. Smaller particles near the planet’s surface have been shown to cause respiratory problems in humans.
Mauldin said the newly discovered oxidant might help explain recent studies that have shown large parts of the southeastern United States might have cooled slightly over the past century. Particulates from sulfuric acid over the forests there may be forming more clouds than normal, cooling the region by reflecting sunlight back to space.
Most of the laboratory experiments for the study were conducted at the Leibniz-Institute for Tropospheric Research in Leipzig, Germany.
Co-authors on the study include Torsten Berndt and Frank Stratmann from the Leibniz-Institute for Tropospheric Research; Mikko Sipilä, Pauli Paasonen, Tuukka Petäjä, Theo Kurtén, Veli-Matti Kerminen and Markku Kulmula from the University of Helsinki in Finland; and Saewung Kim from the National Center for Atmospheric Research in Boulder. Mauldin also is affiliated with NCAR and the University of Helsinki.
The study was funded by the European Commission Sixth Framework program, the Academy of Finland, The Finnish Center of Excellence, the European Research Council, the Kone Foundation, the Väisälä Foundation, the Maj and Tor Nessling Foundation, the Otto Malm Foundation and the U.S. National Science Foundation.